January 1, 2024

Decay Modes

Source - xkcd
Rollover text - Unlike an Iron Age collapse, a Bronze Age collapse releases energy, since copper and tin are past the iron peak on the curve of binding energy.

...so, it's funny because...

We haven't taught nuclear decay or nuclear chemistry in my first year chemistry class at Princeton in quite a few years since it was taken out of the Ohio chemistry curriculum and off of the AP exam quite a few years ago. We leave that nuclear stuff to the PHS physics department.

With all that being said, I remember the top row of decay mechanisms, and they're real. 
  • Alpha decay sees the nucleus shedding two protons and two neutrons.
  • Beta decay shows a neutron turning into a proton while the nucleus ejects an high-energy electron, aka a beta particle. That drawing helps us to know that Randall is drawing neutrons as shaded-in circles and protons as the 'white' or 'hollow' spheres.
  • Gamma has the nucleus rearrange its particles - protons and neutrons, known collectively as baryons (though there are more baryons than just protons and neutrons.)
  • Electron capture is just what it says: an electron is drawn into the nucleus, turning a proton into a neutron.
  • Positron emission is also a proton turning into a neutron, but in this case it releases a position, effectively an electron with a positive charge.
  • Neutron emission is pretty self-explanatory as a neutron leaves the nucleus.
Then we get to the made-up ones which lead to the jokes. For some of these, I did rely on explainxkcd to get the gist.
  • Baryon panic would be insanely energetic, requiring all of the protons and neutrons to spontaneously separate, requiring a massive amount of energy to be absorbed by the nucleus.
  • Omega decay is the assumed progression of alpha, beta, and gamma decay - omega being the last Greek letter in the alphabet. I guess since alpha, beta, and gamma decay give off increasingly energetic particles, omega decay would somehow give off the most energetic particle and cause death?
  • Electron wilt seems to show the electrons just stopping their motion around the nucleus, wilting like a flower.
  • One big nucleon shows all of the protons and neutrons 'congealing' into a single nucleon, the generic term for a particle in the nucleus. The is, I guess, kind of like a Bose-Einstein condensate but for the nucleus.
  • Fungal decay gets nuclear decay and biological decay muddled up with the nucleus sprouting mushrooms.
  • Collapse due to invasion by the sea peoples seems to refer to something that supposedly happened to the eastern Mediterranean during the late Bronze Age. I dunno. I had to look it up.
The rollover makes reference to the fact that the nuclear binding energy for iron-56 is the highest on the periodic table (at least among common isotopes). This is why large stars never make anything beyond iron-56 in their life cycle until they go supernova. And since bronze is made of tin and copper - both beyond iron-56 on the periodic table - a collapse of those elements releases energy according to Randall.

It's all some pretty esoteric stuff today.

Don't worry if you don't get it.


 

December 25, 2023

Redox Reaction: Holiday ChemisTree! Copper + Silver Nitrate (Holiday Chemistry)

I swear that it it total serendipity that I'm posting this on Christmas.

I schedule posts way in advance (10/1/23 is when I'm posting this one) and don't pay any attention as to when they get posted. I just line things up so they're on the next available Monday. 

We couldn't get any better a time to see the redox reaction between a silver nitrate solution and a copper Chemistree, could we?

December 18, 2023

pH Tweet

 


See, it's funny because a pH 10 solution would be basic.

The joke subverts your expectations. You see the, "[y]ou're a 10..." and think it's going to be a compliment, that the 10 is on a scale of 0-10.

But, no...they've put the 10 on a logarithmic pH scale where 10 means that the solution contains 1 x 10-10 moles of H+ ions per liter of solution.

Hah, take that!

You've been served!

December 11, 2023

WaterLight - The clean energy revolution is here

I'm skeptical, I will admit it.

I want this light to work; I really do. But I also have to apply the Sagan standard to the light, and none of these videos or articles seem to provide that extraordinary evidence to me.

I keep coming back to the fact that the whole thing just sounds like a nicely engineered magnesium/copper cell with salt water (or urine) as the electrolytic path between the electrodes.

The magnesium electrode is going to run out. That's what anodes do.

Read more, please, and explain to me how I'm wrong. Sadly I haven't been able to find an actual schematic of the WaterLight anywhere.

December 4, 2023

Removing tarnish from silver

Usually when I turn to Compound Interest, I'm looking to find a gorgeous infographic explaining some aspect of chemistry. Today's post from them (him, really), isn't graphical in the least. Instead, it's an in-depth exploration of one of the NACE labs that we perform in our summer, teacher camps: Quicksilver.

Why does the sodium bicarbonate need to be there? Andy explains.

Why do we need the salt? Andy explains.

Where does the rotten egg smell come from? Andy explains.

Why do people still buy polishing plates for as much as $30? Even Andy can't explain that.

Compound Interest is a British blog through which Andy Brunning, a chemistry teacher with a flair for graphic design, posts outstanding chemistry-themed infographics.

November 27, 2023

Brainiac's alkali metals were FAKED!

The Brainiac video purports to show the explosions of alkali metals - rubidium and cesium - in a bathtub partially filled with water. The explosions are faked. They're bull-pucky. 

There is an honest video - I think - of the alkali metals going into water thanks to World of Chemistry and Roald Hoffman.

There are also videos from Periodic Table of Videos from the University of Nottingham that go through information - not just the explosions in water - of the alkali metals.

The above video explains why the Brainiac videos are faked from a thermodynamic basis.

Don't trust the internet, folks.

November 20, 2023

The Hunt For Green Helium

Helium is a noble gas, so the helium itself is already green. The helium itself doesn't do any damage to the environment.

However, we only find the helium in pockets of methane meaning that any hunt for helium is really a hunt for methane - a really effective greenhouse gas.

The video explains that scientists are now hunting down pockets of nitrogen with helium rather than methane with helium. That would be a big find.