August 29, 2022

The Scientist Who Killed Millions and Saved Billions

Sam Kean told much of this story in his excellent book, The Disappearing Spoon (primarily in chapter 5 - and I know that this link has to be flouting copyright law entirely). 

There are details here that I didn't know, but the story of Haber should be more well known. He was one of the most brilliant scientific minds of our modern world, but he was - in a charitable description - more concerned with the science than with the ethics of his science. In a less charitable description, Haber was a bastard.

He found a way to synthesize ammonia from nitrogen in the atmosphere, a discovery that lead to modern fertilizers which allowed us to become a world of nearly 8 billion people and prove the Malthusians wrong.

That discovery is one of the most important in shaping our world. 

He absolutely deserved his Nobel prize. 

He also found a way to turn that fertilizer into explosives for the Germans in World War I.

And he developed a way to produce chlorine gas which was then used on the battlefield, choking soldiers in merciless, painful ways.

...for which Haber was promoted in the German army.

His wife killed herself - possibly because of his involvement in chemical weapons - and Haber headed onward to the front to supervise more use of chlorine gas.

Oh, and Haber's institute developed Zyklon B, the gas used in the gas chambers on the German concentration camps.

(Great animation at 9:30, by the way)


August 22, 2022

Chemist Breaks Down 22 Chemistry Scenes From Movies & TV | WIRED

I'm a sucker for these 'expert-watches-tv-and-movies-and-comments' style of videos.

In order, you get...

  • Breaking Bad - HF isn't the best choice for dissolving a body, and Walt should wear goggles.
  • It's Always Sunny in Philadelphia - Don't huff gasoline.
  • Rick & Morty - Their recipe for oven-less brownies isn't real. Shocking, eh?
  • Spider-man: Homecoming - Carbon makes four bonds...not two or one. I actually, kind of disagree here because organic chemists often omit the hydrogens in their drawing. I've done the demo she does at 4:00. We do it in our material science class at Princeton every year.
  • Black Panther - Vibranium isn't real, but elements do come to Earth via asteroid.
  • Breaking Bad - Walt and Jessie wear good PPE when cooking meth, and the synthesis uses real glassware and procedures - but maybe not for meth.
  • Zoolander - Don't have a gas fight, but luckily you would likely need a bigger spark to make that explosion.
  • Christmas Vacation - Sewer gas maybe could explode, especially hydrogen sulfide (H2S), but probably not like it shows.
  • Con Air - Cigarettes dropped into a trail of gasoline isn't going to make a fire like that.
  • Community - Chloroform doesn't act that quickly.
  • Blow - Chemists to test for purity with melting points. That's f'real...but the instrument shown is odd.
  • Fight Club - Lye doesn't burn like that. Acids burn more like that.
  • The Big Bang Theory - I've already said I hate this show, but their science is pretty good here. Elephant toothpaste is f'real.
  • Spider-man - "It's just garbage."
  • Chernobyl - "His explanation of a nuclear reactor is beautiful. I love it."
  • Chernobyl - Yes, xenon is useful in nuclear reactors, and hydrogen explosions really happened in Chernobyl.
  • Mr Bean: The Whole Bean - Mr Bean should wear goggles, and his glassware is all set up backwards.
  • Terminator 2: Judgement Day - A liquid metal frozen in liquid nitrogen could cause shattering...maybe...but it wouldn't look like that.
  • Radium Girls - Very accurate and sadly deadly
  • National Treasure - There are invisible ink recipes, but the movie version is fakey.
  • Casino Royale - Sodium cyanide is very soluble. Could work, might make Bond look sickly like that. There's more to neutralizing the poison than the movie shows.
  • The Rock - VX nerve agent is real but doesn't look like that. The green beads are pretty but not real.
  • The Martian - Yeah, you could burn hydrazine like that - at least chemically - but it would likely explode like it does in the movie. He should have way more PPE to use it.
From what I've read, Kate the Chemist's bona fides seem to be f'real, too. Her squeals during her demos, though, don't do it for me.

August 15, 2022

Chemicals

 

Source - https://xkcd.com/2648/

See, it's funny because just knowing which atoms - and even how many of each of those atoms - constitute a molecule doesn't mean that you can synthesize that molecule.

There's an analogy here to cooking. If I list the ingredients - even if I include the amounts of each ingredient - for a recipe, that doesn't give you enough information actually to make that final product. Listing the ingredients for a chocolate cake, for example, doesn't tell you in which order the ingredients should be assembled, nor does it tell you how to handle each of those ingredients. Do you whip the butter, fold it in, melt it, freeze it, crumble it into the flour?

That analogy, though, even undersells the complexity of molecules, however, because not all atoms will assemble in the ways we want them to assemble. Some molecules require very specific pathways to produce. 

To read this explanation in far more words, check out explainxkcd.com.

August 8, 2022

There are two types of smoke alarm. One of 'em ain't so good.

I've always told my students that smoke detectors contain americium, a man-made, radioactive element.

Looks like the older style of smoke detectors does contain americium but that the newer - light detecting style - actually doesn't.

I'm going to have to check my smoke detectors to see which type I have at home.

August 1, 2022

Why Steel from Before 1945 is Weirdly Expensive

Steel...and a whole lot of other things...changed when the world when the first atomic bomb was tested in New Mexico in 1945.

Today's video details why the steel produced post-1945 isn't useful for anything needed to shield against radiation because it's radioactive itself...and why lead from Mediterranean shipwrecks is equally as useful.

Most of the video above is correct, though I will point out that "Scarpa Bay" is probably actually Scapa Flow. I know. I've been there. 

Relatedly, check out Veritasium's video on how Kodak found out about the atomic bomb waaaaaay before the US government intended to tell anybody.

July 25, 2022

Periodic Table Changes

Source - XKCD

See, it's funny because the periodic table isn't the shape it is because of any sort of design sense. There are all sorts of details that would look or seem better if they were changed, but they can't be changed because they're based on properties, electron configurations, and property similarities - not on what would look neat.

See, the periodic table is appropriately periodic meaning there's a repeating pattern in its layout. In this case there's a repeating pattern in the properties of the elements when the elements are placed in order by their atomic number. Lithium is similar to sodium which is similar to potassium and on down with rubidium, cesium, and francium. With those similarities noticed, the elements were placed in columns with a new row (or period) starting every time those properties repeated.

It would be nice to see helium moved above beryllium, and there are some reasons why it maybe should be moved over there, but there are way more reasons why it belongs in column 18 with the noble gases.

Admittedly, changing the element symbols (iron = Fe but maybe should be I...silver = Ag but maybe should be Sv, and so on) is within the powers of a bunch of chemists if they really wanted to do it, but just moving the inner transition metals so they don't look dorky down at the bottom of the table isn't within the powers of those same chemists because it would require those elements to have different properties and different electron configurations. Those aren't things chemists have the power to change.

Maybe next week I'll rant about all the non-periodic periodic tables that I get shown in the course of my job.

July 18, 2022

This Chemical Cuts Like a Knife

I appreciate the note at the beginning of the video, "Hoping YouTube doesn't flag my video".

The YouTube algorithm is tricky and must be appeased.

The reactions shown, however, aren't all that tricky.

ferric chloride = iron(III) chloride = FeCl3
sodium fluoride = NaF
potassium thiocyanate = KSCN

The first reaction, the one that produces the 'blood' is this one...

FeCl3 + 3 KSCN --> Fe(SCN)3 + 3 KCl

The 'blood' is the iron(III) thiocyanate. The initial reactants here are slightly yellow (FeCl3) and colorless (KSCN).

The 'healing' reaction then is between the iron(III) thiocyanate and sodium fluoride to produce a complex ions.

Fe(SCN)3 + 6 NaF --> Na3[FeF6] + 3 NaSCN

The Na3[FeF6] is a colorless, complex ion called hexafluoroferrate(III).

I'm not sure what the disposal of the thiocyanate compound is, but the complex ion should be mostly fine for easy disposal.

Source of reaction - link